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Asymmetric Synthesis of Enantioenriched (+)-Elaeokanine A

โœ Scribed by Dieter, R. Karl; Chen, Ningyi


Book ID
120607954
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
86 KB
Volume
71
Category
Article
ISSN
0022-3263

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โœ Schmitthenner, Hans F.; Weinreb, Steven M. ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 240 KB
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โœ Joseph J. Tufariello; Sk.Asrof Ali ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 199 KB

The synthesis of dl-elaeokanine-A and dl-elaeokanine-C is described by an approach which utilizes a nitrone cycloaddition to generate a B-aminoketone, which upon annulation produces one or the other of the title alkaloids depending upon conditions. We wish to describe herein a synthetic entry into t