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Asymmetric Synthesis of Deoxypolypropionate Units via Stereoselective Hydrogenation of Optically Active Cycloheptatriene

✍ Scribed by Sugimura, Takashi; Sato, Yasuhiro; Im, Chun Young; Okuyama, Tadashi


Book ID
126845829
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
76 KB
Volume
6
Category
Article
ISSN
1523-7060

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A chiral Ru(II) complex, RuCl[(S,S)-N-(p-toluenesulfonyl)-1,2-diphenyl-ethylenediamine](p-cymene), serves as an efficient catalyst for asymmetric transfer hydrogenation of 2-acetylpyridine with a substrate to catalyst molar ratio of 200-1000 with HCOOH as a hydrogen source to give (S)-1-(2-pyridyl)e