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Asymmetric synthesis of an enantiomerically pure rivastigmine intermediate using ketoreductase

✍ Scribed by Sethi, Madhuresh K.; Bhandya, Somashekar R.; Maddur, Nagaraj; Shukla, Rohit; Kumar, Anish; Jayalakshmi Mittapalli, V.S.N.

Book ID: 120194885
Publisher: Elsevier Science
Year: 2013
Tongue: English
Weight: 264 KB
Volume: 24
Category: Article
ISSN: 0957-4166
DOI: 10.1016/j.tetasy.2013.01.023

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## Abstract A novel method for the synthesis of __N__‐methylserines has been developed. The oxazolidines 4 are formed by condensation of the serine methyl esters 1 with formaldehyde. These intermediates are subsequently reduced to the __N__‐methylserine methyl esters 9 by an acid‐catalyzed ring ope