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Asymmetric Synthesis of (+)-Altholactone: A Styryllactone Isolated from Various Goniothalamus Species

✍ Scribed by Dieter Enders; Julien Barbion

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
356 KB
Volume
14
Category
Article
ISSN
0947-6539

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✍ Ana C. Allepuz; Ramón Badorrey; María D. Díaz-de-Villegas; José A. Gálvez 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB

## Abstract The asymmetric synthesis of (2__S__,3__R__)‐2‐amino‐3‐octanedecanol hydrochloride (ES‐285**·**HCl) was achieved in eight steps in ca. 38 % overall yield from the __N__‐benzylimine‐derived from (__R__)‐2,3‐__O__‐isopropylidene glyceraldehyde, which is easily available on gram scale from