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Asymmetric synthesis of alkaloids using polyfunctionalized chiral building blocks

✍ Scribed by Franklin A. Davis; Bin Chao; Yemane W. Andemichael; Pradyumna K. Mohanty; Tianan Fang; David M. Burns; Ashwin Rao; Joanna M. Szewczyk

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 192 KB
Volume: 13
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.10090

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✦ Synopsis

Abstract

Enantiopure N‐sulfinyl‐δ‐amino‐β‐ketoesters and isoquinolones, prepared from sulfinimines (N‐sulfinyl imines) are a new class of polyfunctionalized chiral building blocks. These building blocks provide easy access to enantiomerically pure, functionalized piperidines and tetrahydroisoquinolines with a minimum of chemical manipulation and protecting‐group chemistry. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:486–492, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10090

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