Asymmetric double hydroboration of 1,3-d
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Yonetatsu Matsumoto; Tamio Hayashi
📂
Article
📅
1991
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Elsevier Science
🌐
French
⚖ 310 KB
Suntnuzry: Reaction of I-phenyl-1,3-butadiene with catecholborane in the presence of a rhodium catalyst bearing ~a~lphosphine ligand such as PPh3 or dppf proceeded regioselectively to give, after oxidation, anti-l-phenyl-1,3-butanediol in a good yield. Use of (R)-BINAP as a chiral ligand for the cat