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Asymmetric Synthesis of 3,3-Diarylpropanals with Chiral Diene—Rhodium Catalysts.

✍ Scribed by Jean-Francois Paquin; Christian Defieber; Corey R. J. Stephenson; Erick M. Carreira


Publisher
John Wiley and Sons
Year
2005
Weight
24 KB
Volume
36
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES


Asymmetric double hydroboration of 1,3-d
✍ Yonetatsu Matsumoto; Tamio Hayashi 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 310 KB

Suntnuzry: Reaction of I-phenyl-1,3-butadiene with catecholborane in the presence of a rhodium catalyst bearing ~a~lphosphine ligand such as PPh3 or dppf proceeded regioselectively to give, after oxidation, anti-l-phenyl-1,3-butanediol in a good yield. Use of (R)-BINAP as a chiral ligand for the cat