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Asymmetric Synthesis of 2-Alkenyl-1-cyclopentanols via Tin−Lithium Exchange and Intramolecular Cycloalkylation

✍ Scribed by Christoph, Guido; Hoppe, Dieter

Book ID
127336425
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
61 KB
Volume
4
Category
Article
ISSN
1523-7060

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Asymmetric synthesis of erythro- and threo-2-(1-hydroxyalkyl)piperidines via iodocyclocarbamation of 1-acyl-2-alkenyl-1,2,3,6-tetrahydropyridines
✍ Daniel L Comins; Alfred L Williams 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 121 KB

An iodocyclocarbamation procedure has been developed for the stereoselective preparation of erythro-and threo-2-(1-hydroxyalkyl)piperidines. This methodology was utilized in the asymmetric synthesis of two piperidine alkaloids, (+)-α-conhydrine and (+)-β-conhydrine.