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Asymmetric Synthesis in the Presence of Cyclodextrins

✍ Scribed by Francesco Trotta; Giancarlo Cravotto; Stefano Rossignoli

Book ID
110432572
Publisher
Springer Netherlands
Year
2002
Tongue
English
Weight
68 KB
Volume
44
Category
Article
ISSN
0923-0750

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Asymmetric cyclopolymerization of N-tert
Asymmetric cyclopolymerization of N-tert-butyl-N-allylacrylamide in the presence of Ξ²-cyclodextrin
✍ Makiko Seno; Toshiya Ikezumi; Takafumi Sumie; Yasuhito Masuda; Tsuneyuki Sato πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 162 KB πŸ‘ 2 views

The radical polymerization of N-tert-butyl-N-allylacrylamide (t-BAA) was carried out in a dimethyl sulfoxide/H 2 O mixture in the presence of ␀-cyclodextrin (␀-CD). The polymerization proceeded with the complete cyclization of the t-BAA unit and yielded optically active poly(t-BAA). The IR spectrum