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Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes. 2. Nickel- and palladium-catalyzed asymmetric Grignard cross-coupling

โœ Scribed by Hayashi, Tamio; Konishi, Mitsuo; Fukushima, Motoo; Mise, Takaya; Kagotani, Masahiro; Tajika, Masatoyo; Kumada, Makoto

Book ID
117994191
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
984 KB
Volume
104
Category
Article
ISSN
0002-7863

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Asymmetric synthesis catalyzed by chiral
Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition-metal complexes. 6. Practical asymmetric synthesis of 1,1'-binaphthyls via asymmetric cross-coupling with a chiral [(alkoxyalkyl)ferrocenyl]monophosphine/nickel catalyst
โœ Hayashi, Tamio.; Hayashizaki, Keiichi.; Kiyoi, Takao.; Ito, Yoshihiko. ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 606 KB

averaged. The concentration of the free amide remaining after complexation could then be calculated from the extinction coefficient and used to determine the apparent equilibrium constant. The equilibrium between free amide and the sec-butyllithium-amide complex was established within less than ca.