Asymmetric Synthesis and Cycloaddition Chemistry of Trans-2-Methylene-1,3-Dithiolane 1,3-Dioxide
β Scribed by Aggarwal, Varinder K.; Grainger, Richard S.; Spargo, Peter L.
- Book ID
- 118071071
- Publisher
- Taylor and Francis Group
- Year
- 1994
- Tongue
- English
- Weight
- 112 KB
- Volume
- 95
- Category
- Article
- ISSN
- 1042-6507
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π SIMILAR VOLUMES
Carbon black-supported sulfuric acid or BF 3 β Et 2 O-initiated polymerizations of 2-methylene-4,4,5,5-tetramethyl-1,3-dioxolane (1), 2-methylene-4-phenyl-1,3-dioxolane (2), and 2-methylene-4-isopropyl-5,5-dimethyl-1,3-dioxane (3) were performed. 1,2-Vinyl addition homopolymers of 1-3 were produced u
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract We report the ready asymmetric synthesis of nucleoside analogues containing a 1,3βdithiolane ring that mimics the sugar moiety of natural nucleosides. The synthesis is accomplished in three main steps from benzoyloxyethanal 1,3βdithiolane, the key step being its conversion into a chiral