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Asymmetric synthesis. 2. Practical method for the asymmetric synthesis of indolizidine alkaloids: total synthesis of (-)-monomorine I

โœ Scribed by Royer, Jacques; Husson, Henri Philippe

Book ID
125898984
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
559 KB
Volume
50
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

A concise asymmetric synthesis of 5,8-di
A concise asymmetric synthesis of 5,8-disubstituted indolizidine alkaloids. Total synthesis of (โˆ’)-indolizidine 209B
โœ Yongcheng Song; Sentaro Okamoto; Fumie Sato ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 112 KB

A general access to 5,8-disubstituted indolizidine alkaloids has been developed, where the asymmetric addition of an optically active allenyltitanium to benzyl[4-(tert-butyldimethylsilyloxy)butylidene]amine (2) is the key reaction. As a typical example, (-)-indolizidine 209B was efficiently synthesi