Asymmetric Sulfoxidation of Thioethers with Hydrogen Peroxide in Water Mediated by Platinum Chiral Catalyst
β Scribed by Alessandro Scarso; Giorgio Strukul
- Book ID
- 101419235
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 229 KB
- Volume
- 347
- Category
- Article
- ISSN
- 1615-4150
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π SIMILAR VOLUMES
Eight chiral Schiff-base ligands were prepared from (S)-tert.-leucinol and four chiral, racemic salicylic aldehydes. The resulting pairs of diastereomers were separated by preparative HPLC and applied to the vanadium-catalyzed asymmetric sulfoxidation of thioethers with hydrogen peroxide. The produc
Schiff-Base Ligands Carrying Two Elements of Chirality: Matched-Mismatched Effects in the Vanadium-Catalyzed Sulfoxidation of Thioethers with Hydrogen Peroxide. -Chiral Schiff base ligands prepared from (S)-tert-leucinol and chiral salicylic aldehydes are investigated in the vanadium-catalyzed asym