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Asymmetric reduction of prochiral ketones with borane using chiral squaric amino alcohols derived from camphor as catalysts

✍ Scribed by Hai-Hua Zou; Jian Hu; Ji Zhang; Jing-Song You; Dan Ma; Ding Lü; Ru-Gang Xie

Book ID
108211579
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
185 KB
Volume
242
Category
Article
ISSN
1381-1169

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Easily available D-(+)-camphor-derived chiral mercapt\*alcohols 2 and 3 were employed for catalytic asymmetric borane reduction of aromatic ketones. Moderate enantioselectivities with e.e. 20.2-72.1% were obtained with 10 mol% catalyst. Opposite asymmetric induction was achieved' when mercaptc-alcoh

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v