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Asymmetric reduction of phenylα- andβ-dialkylamino ketones by treatment with optically active organomagnesium compounds

✍ Scribed by L. D. Tomina; E. I. Klabunovskii; Yu. I. Petrov; E. D. Lubuzh; E. M. Cherkasova


Book ID
112421330
Publisher
Springer
Year
1972
Tongue
English
Weight
356 KB
Volume
21
Category
Article
ISSN
1573-9171

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This work reports the catalytic reduction, via hydrogen-transfer from propan-2-ol, of various a ,b-unsaturated ketones or w Ž .Ž .x Ž . unsymmetrical ketones in the presence of Ir COD OMe and the chiral aminodiphosphine ligands R -2 ) Ž . Ž . Ž . Ž . Ž . ) Ž . Ž . PhC H Me N CH CH PR R s Ph, Cy and