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Asymmetric reduction of ketones with sodium aluminum hydride modified by various chiral diols

✍ Scribed by M. G. Vinogradov; L. S. Gorshkova; V. A. Pavlov; O. V. Mikhalev; G. V. Chel'tsova; I. V. Razmanov; V. A. Ferapontov; O. R. Malyshev; G. L. Heise

Publisher: Springer
Year: 2000
Tongue: English
Weight: 458 KB
Volume: 49
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf02494775

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The recent findings that 2-oxazolines are inert to lithium aluminum hydride' and the successful implementation of a chiral non-racemic oxazoline as a reagent in asymmetric synthesis 2s3 have prompted a study involving oxazoline-hydrides as chiral reducing agents. Several chiral nonracemic oxazolines