Asymmetric reduction of aromatic ketones with chiral alkoxy-amineborane complexes
β Scribed by Hirao, Akira; Itsuno, Shinichi; Nakahama, Seiichi; Yamazaki, Noboru
- Book ID
- 118166729
- Publisher
- The Royal Society of Chemistry
- Year
- 1981
- Tongue
- English
- Weight
- 201 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0022-4936
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Chiral cobalt--diamine complexes have been prepared and tested in catalytic reduction of 13-ketoesters and ketones with molecular hydrogen or hydride transfer reduction (HTR). Modest to high conversions, but low e.e.s were obtained in the first case, whereas encouraging e.e.s (up to 58%) but low con
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