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Asymmetric photoreaction of a diarylethene in hydrogen-bonded cocrystals with chiral molecules

✍ Scribed by Ichikawa, Tomohiro ;Morimoto, Masakazu ;Irie, Masahiro

Book ID
121252093
Publisher
Royal Society of Chemistry
Year
2014
Tongue
English
Weight
564 KB
Volume
13
Category
Article
ISSN
1474-905X

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Chiral phosphonium salts having two NI-I and two OH groups as hydrogen-bond donors have been synthesized as novel phase-transfer catalysts, and used for asymmetric alkylation of J~-keto esters to give the corresponding products with up to 50% Β’e.