Asymmetric Oxidative Dimerization of the Enolates of N-(Bis(methylthio) methylene)-and N-(Diphenylmethylene)glycine Esters. -A new method for the synthesis of threo 3-aminoaspartates such as (II) via asymmetric oxidative dimerization of title compounds such as (I) is presented. The stereochemical ou
✦ LIBER ✦
Asymmetric Oxidative Dimerization of the Enolates of N -[Bis(methylthio)methylene]- and N -(Diphenylmethylene)glycine Esters
✍ Scribed by Alvarez-Ibarra, Carlos; Csákÿ, Aurelio G.; Colmenero, Belén; Quiroga, M. Luz
- Book ID
- 126236868
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 130 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3263
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New aspects of the acylation reaction of the aza-allyl anions derived from l and 2 have becn studied. Under suitable reaction conditions, oxazoles 5, ~,a~lisubstituted c~-acyl--ot-amino acid derivatives 3, and ~,3-didehydroamino acid derivatives 7 can be prepared. A new 1,3-diamino-2-propanol deriva
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