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Asymmetric oxidative coupling polymerization of dihydroxynaphthalene derivatives with cobalt-salen complexes

✍ Scribed by Shigeki Habaue; Hideharu Aoyagi; Soichiro Murakami; Hideyuki Higashimura

Book ID: 106001257
Publisher: Springer
Year: 2007
Tongue: English
Weight: 227 KB
Volume: 59
Category: Article
ISSN: 0170-0839
DOI: 10.1007/s00289-007-0771-z

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## Abstract Catalytic properties of a series of chiral (pyrrolidine salen)Mn(III) complexes for asymmetric oxidation of aryl methyl sulfides were evaluated. Moderate activity, good chemical selectivity and low enantioselectivity were attained with iodosylbenzene as a terminal oxidant. Enantioselect