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Asymmetric oxidation of achiral selenides to optically active selenoxides : Stereochemistry of the allyl selenoxide-selenenate [2,3] sigmatropic rearrangement

โœ Scribed by Franklin A. Davis; Orum D. Stringer; John P. McCauley Jr.


Book ID
108374466
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
800 KB
Volume
41
Category
Article
ISSN
0040-4020

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First synthesis of optically pure selenu
โœ Noriyuki Kurose; Tamiko Takahashi; Toru Koizumi ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 740 KB

The first synthesis of optically pure selenuranes 1 has been accomplished by utilizing 2exo-hydroxy-10-bomyl group as a chiral ligand. Complete retention of the configuration has been observed in alkaline hytl'olysis of 1 to give selenoxides 2. The structure of 1 and2 has been fully established by X