Asymmetric Nickel-Catalyzed Hydrocyanation of Vinylarenes by Applying Homochiral Xantphos Ligands
✍ Scribed by Wolfgang Goertz; Paul C. J. Kamer; Piet W. N. M. van Leeuwen; Dieter Vogt
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 106 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0947-6539
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## Abstract A series of chiral (__R__)‐binaphthol‐based diphosphite ligands with different substituents was prepared and applied in the asymmetric nickel‐catalyzed hydrocyanation of styrene and 1,3‐cyclohexadiene to investigate the influence of their steric properties. The optimum steric properties