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Asymmetric NH Insertion Reaction Cooperatively Catalyzed by Rhodium and Chiral Spiro Phosphoric Acids

✍ Scribed by Bin Xu; Prof. Shou-Fei Zhu; Xiu-Lan Xie; Jun-Jie Shen; Prof. Qi-Lin Zhou

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
342 KB
Volume
123
Category
Article
ISSN
0044-8249

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## Abstract **Letβ€²s resolve our differences**: Implementation of an enantioselective Michael addition followed by an intramolecular aldol reaction catalyzed by two phosphoric acids has enabled the synthesis of cyclohexenone derivatives with excellent enantioselectivities. Prominent kinetic resoluti