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Asymmetric Michael Addition Induced by the Anion of an Imidazolium Salt

✍ Scribed by Vincent Gauchot; Julien Gravel; Andreea R. Schmitzer

Book ID
115555504
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
433 KB
Volume
2012
Category
Article
ISSN
1434-193X

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Asymmetric Michael addition of trisubsti
Asymmetric Michael addition of trisubstituted carbanion to nitroalkenes catalyzed by sodium demethylquinine salt in water
✍ Fu-Xin Chen; Cheng Shao; Qian Liu; Pin Gong; Chun-Liang Liu; Rui Wang πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 137 KB

## Abstract A mild method for the asymmetric synthesis of quaternary and tertiary carbon centers has been developed through Michael addition of trisubstituted carbon nucleophile to nitroalkenes catalyzed by low loading sodium demethylquinine salt in water. Chirality, 2008. Β© 2009 Wiley‐Liss, Inc.