𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Asymmetric Mannich-Type Reactions for the Synthesis of Aspartic Acid Derivatives from Chiral N - tert -Butanesulfinylimino Esters

✍ Scribed by Jacobsen, Mikkel F.; Skrydstrup, Troels


Book ID
127023433
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
65 KB
Volume
68
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Asymmetric Mannich-Type Reaction of a Ch
✍ Cui-Hua Zhao; Li Liu; Dong Wang; Yong-Jun Chen πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 201 KB πŸ‘ 1 views

## Abstract Deprotonation of the chiral __N__‐(__tert__‐butylsulfinyl) ketimine **1** followed by trapping with imines **2** afforded the β‐aminoimines **3** as the Mannich‐type products in high diastereoselectivities (99:1 __dr__). As versatile synthons chiral β‐amino imines **3** could be transfo