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Asymmetric Mannich-Type Reaction Catalyzed by Palladium Complexes.

โœ Scribed by Fujii, Akio; Hagiwara, Emiko; Sodeoka, Mikiko

Book ID
118228733
Publisher
The Society of Synthetic Organic Chemistry, Japan
Year
2000
Tongue
Japanese
Weight
425 KB
Volume
58
Category
Article
ISSN
0037-9980

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Amine-catalyzed direct asymmetric Mannic
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โœ Wolfgang Notz; Kandasamy Sakthivel; Tommy Bui; Guofu Zhong; Carlos F Barbas III ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 82 KB

Three chiral cyclic secondary amines are shown to be catalysts for the direct asymmetric Mannich-type reaction of acetone with a variety of preformed aldimines derived from o-anisidine. A simple one-pot three-component reaction procedure consisting of aldehyde, acetone, p-anisidine and an amine cata