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Asymmetric induction via addition-elimination process: nitroolefination of .alpha.-substituted lactones

✍ Scribed by Fuji, Kaoru.; Node, Manabu.; Nagasawa, Hideko.; Naniwa, Yoshimitsu.; Terada, Shunji.


Book ID
111899467
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
272 KB
Volume
108
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Asymmetric Michael
✍ D. Enders; Pascal Teschner; Robert Groebner; Gerhard Raabe πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 2 views

Asymmetric Michael Additions via 6-and 7-Membered Lactone SAMP-Hydrazones: Diastereo-and Enantioselective Synthesis of Substituted Lactone Esters. -High asymmetric inductions are achieved in the Michael addition of hydrazones (I) to Ξ±,Ξ²-unsaturated esters (II). Removal of the chiral auxiliary by ozo