Asymmetric induction on the Schiff bases
✍ Scribed by G. Bérubé; K. Jankowski
- Book ID
- 104221750
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 106 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Oxidation of chiral Schiff bases leads to nonracemic diasterometric oxaziridines with a preferential formation of an E isomer.
📜 SIMILAR VOLUMES
## The condensation of racemic 2-norbornanone and chiral a-phenylethylamine has been shown to produce four diastereomeric Schiff bases rather than only one as previously reported.
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Asymmetric amination of glycine Schiff bases with azodicarboxylates has been developed with high yields and up to 98% ee using AgOAc/Taniaphos complex as the catalyst.