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Asymmetric induction in the solid state photochemistry of salts of carboxylic acids with optically active amines

✍ Scribed by Anna D. Gudmundsdottir; John R. Scheffer


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
170 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis


crystal-to-single crystal) behavior. In the present communication we describe our initial results in this area.


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Asymmetric induction through the use of
✍ Eugene Cheung; Matthew R Netherton; John R Scheffer; James Trotter; Alla Zenova πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 87 KB

Attachment of chiral auxiliaries to 2-benzoyladamantane-2-carboxylic acid, either covalently through ester formation with optically pure alcohols, or ionically via salt formation with optically pure amines, leads to substrates whose irradiation in the crystalline state affords chiral rearranged phot