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Asymmetric induction in the addition of chiral carbalkoxycarbenoids to styrene

✍ Scribed by Krieger, Paul E.; Landgrebe, John A.

Book ID: 127108216
Publisher: American Chemical Society
Year: 1978
Tongue: English
Weight: 957 KB
Volume: 43
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00417a011

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## Abstract 1,4‐Additions of PhCu · BF~3~, __n__‐Bu · BF~3~ and MeCu · BF~3~ to the __trans__‐8‐phenyl‐menthyl enoates **1** proceeded with high chiral induction. Saponification of the resulting esters **2** gave the corresponding enantiomerically pure β‐substituted alkanoic acids **3** and the rec