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Asymmetric induction III. Effect of the t-butyl group directly bonded to the carbonyl

✍ Scribed by Gerasimos J. Karabatsos; Christina Zioudrou; Irene Moustakali


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
172 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis


In order to establish the limits of applicability of our model of asymmetric inductionl, we began studies designed to probe initially the soundness of the assumptions upon which the model is based. Raving cmnted* previously on .the question of bond breaking and making at the transition state, we focus attention in this ccmvnunication on a consequence of one of the basic assumptions of the model.


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