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Asymmetric hydrogenations catalysed by diphosphinite rhodium complexes derived from natural tartaric acid

✍ Scribed by Jean Bourson; Laureano Oliveros


Book ID
108351446
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
550 KB
Volume
229
Category
Article
ISSN
0022-328X

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Asymmetric Transfer Hydrogenation of Ket
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## Abstract Amino acid based thioamides, hydroxamic acids, and hydrazides have been evaluated as ligands in the rhodium‐catalyzed asymmetric transfer hydrogenation of ketones in 2‐propanol. Catalysts containing thioamide ligands derived from L‐valine were found to selectively generate the product w