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Asymmetric hydrogenation of α- or β-acyloxy α,β-unsaturated phosphonates catalyzed by a Rh(i) complex of monodentate phosphoramidite

✍ Scribed by Zhang, Jinzhu; Dong, Kaiwu; Wang, Zheng; Ding, Kuiling


Book ID
120467317
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
123 KB
Volume
10
Category
Article
ISSN
1477-0520

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✍ M. Ángeles Chávez; Sergio Vargas; Andrés Suárez; Eleuterio Álvarez; Antonio Pizz 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 671 KB

## Abstract The enantioselective hydrogenation of β‐(acyloxy)‐ and β‐(acylamino)vinylphosphonates with rhodium catalysts based on chiral phosphane‐phosphite ligands has been studied. In the case of the β‐(acyloxy)vinylphosphonates, the reaction also produces an achiral phosphonate resulting from th