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Asymmetric Hydrogenation of α-Keto Phosphonates with Chiral Palladium Catalysts

✍ Scribed by Nataliya S. Goulioukina; Grigorii N. Bondarenko; Alexei V. Bogdanov; Konstantin N. Gavrilov; Irina P. Beletskaya


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
164 KB
Volume
2009
Category
Article
ISSN
1434-193X

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Asymmetric hydrogenation of α-keto ester
✍ Catherine Pinel; Nelly Gendreau-Diaz; Alexandra Bréhéret; Marc Lemaire 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 396 KB

Asymmetric catalytic hydrogenation of methyl phenylglyoxylate with diamine-chelated metal was studied. Enantiomeric excesses of up to 50% were obtained using a rhodium complex prepared in situ by mixing bis(l,5-cyclooctadiene)dirhodium(I) dichloride with two equivalents of (N,N')dimethyl (1 R,2R)di