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Asymmetric hydrogenation of isophorone in the presence of (S)-proline: Revival of a 20 years old reaction

✍ Scribed by M. Fodor; A. Tungler; L. Vida


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
690 KB
Volume
140
Category
Article
ISSN
0920-5861

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Enantioselective hydrogenation of isopho
✍ Shuang Li; Ensheng Zhan; Yong Li; Yide Xu; Wenjie Shen πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 570 KB

Enantioselective hydrogenation of isophorone and kinetic resolution of 3,3,5-trimethylcyclohexanone (TMCH) over Pd catalysts in the presence of (S)-proline revealed that the enantioselectivity for hydrogenation of isophorone was mainly originated from the kinetic resolution of TMCH. The rapid hydrog