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Asymmetric hydrogenation of aromatic ketones using polymeric catalyst prepared from polymer-supported 1,2-diamine

✍ Scribed by Shinichi Itsuno; Masahiro Chiba; Miyuki Takahashi; Yukihiro Arakawa; Naoki Haraguchi


Book ID
108189241
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
204 KB
Volume
692
Category
Article
ISSN
0022-328X

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Polystyrene-Supported Enantiopure 1,2-Di
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Chlorosulfonylated polystyrene, a commodity resin, reacts with enantiopure 1,2-diamines to afford, in a single step, high loading catalytic resins involving monosulfonylated 1,2-diamino moieties. These functional polymers form stable (p-cymene)ruthenium chloride [RuClA C H T U N G T R E N N U N G (p