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Asymmetric hydrogenation of aromatic ketones in ionic-liquid media catalyzed by Ru-TPPTS–(1S,2S)-DPENDS complexes

✍ Scribed by Wei Xiong; Qi Lin; Hongxia Ma; Hongjie Zheng; Hua Chen; Xianjun Li

Book ID
108283944
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
121 KB
Volume
16
Category
Article
ISSN
0957-4166

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The asymmetric hydrogenation of benzalacetone catalyzed by ruthenium monophosphine complex RuCl 2 (TPPTS) 2 [TPPTS = P(m-C 6 H 4 SO 3 Na) 3 ] modified by (S,S)-DPENDS (disodium salt of sulfonated (S,S)-1,2-diphenyl-1,2-ethylene-diamine) was investigated in a water medium. Under the optimized conditi