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Asymmetric homogeneous hydrogenation of imines using rhodium-phosphine systems

✍ Scribed by William R. Cullen; Michael D. Fryzuk; Brian B. James; James P. Kutney; Guo-J. Kang; Georg Herb; Ian S. Thorburn; Roberto Spogliarich

Book ID: 103693415
Publisher: Elsevier Science
Year: 1990
Weight: 709 KB
Volume: 62
Category: Article
ISSN: 0304-5102
DOI: 10.1016/0304-5102(90)85220-c

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## Abstract Herein we describe the synthesis of a new class of chiral phosphine‐oxazolines and their application as ligands in iridium‐catalyzed hydrogenations. Mechanistic aspects of olefin hydrogenation with this class of iridium catalysts are discussed and a selectivity model to help rationalize