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Asymmetric Henry reaction catalyzed by oxazolinyl Cu(II) complexes

✍ Scribed by Luo Mei; Yin Hao; Zhang Jia Hai; Hu Ke Liang; Pang Wen Min


Publisher
Springer Netherlands
Year
2009
Tongue
English
Weight
441 KB
Volume
35
Category
Article
ISSN
0922-6168

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Asymmetric cyclopropanation catalyzed by
✍ Jian Gao; Shun He Zhong πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 77 KB

The asymmetric cyclopropanation of styrene with alkyl diazoacetate was performed with a series of Cu(II) complexes of novel chiral ligands, which were derived from substitution of 1,3-dibromopropane, 1,2-dibromoethane, ␣,␣ -dibromo-m-xylene and 2,6-bis(bromomethyl)pyridine with 1R, 2S-(-)-ephedrine.