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Asymmetric epoxidation of stilbene by manganese(III) chiral salen complex immobilized in Al-MCM-41

โœ Scribed by Piaggio, Paola; McMorn, Paul; Langham, Christopher; Bethell, Donald; Bulman-Page, Philip C.; Hancock, Frederick E.; Hutchings, Graham J.

Book ID
120290074
Publisher
Royal Society of Chemistry
Year
1998
Tongue
English
Weight
74 KB
Volume
22
Category
Article
ISSN
1144-0546

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The catalytic activity of new chiral sal
The catalytic activity of new chiral salen complexes immobilized on MCM-41 by multi-step grafting in the asymmetric epoxidation
โœ Geon-Joong Kim; Ji-Hoon Shin ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 278 KB

The chiral salen Mn(III) complexes were heterogenized on the siliceous MCM-41 by a new grafting method using (3-aminopropyl) trimethoxysilane and 2,6-diformyl-4-tert-butylphenol. The immobilized chiral salen Mn(III) complexes were stable during the reaction and exhibited a relatively high enantiosel