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Asymmetric Epoxidation of Pentadienols

โœ Scribed by Reinhard Brueckner


Book ID
102003847
Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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Two series of chiral allylic alcohols, derived from c~,~-unsaturated cyanohydrins, were subjected to asymmetric epoxidation under a variety of conditions. Both achiral (organic peracid, metal-catalyzed peroxide) and chiral (Sharpless titanium-tartrate system) oxidants were applied. Several threo and