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Asymmetric epoxidation of functionalized cis-olefins catalyzed by chloroperoxidase

โœ Scribed by Shanghui Hu; Lowell P. Hager

Book ID
104260854
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
206 KB
Volume
40
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Chloroperoxidase catalyzes the asymmetric epoxidation of functionalized cis-2-alkenes with excellent enantioselectivity and good yields, using tert-butyl hydroperoxide as the terminal oxidant.

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Asymmetric Epoxidation of Functionalized cis-Olefins Catalyzed by Chloroperoxidase. -Chloroperoxidase in a buffered solution efficiently catalyzes the asymmetric epoxidation of functionalized cis-olefins (7 examples), using tert-butyl hydroperoxide as the terminal reagent. -(HU, SHANGHUI;

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