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Asymmetric Epoxidation of Conjugated Olefins with Dioxygen

โœ Scribed by Shota Koya; Yota Nishioka; Hirotaka Mizoguchi; Dr. Tatsuya Uchida; Prof. Tsutomu Katsuki

Book ID
112001092
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
535 KB
Volume
51
Category
Article
ISSN
0044-8249

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Chiral ketone-catalyzed asymmetric epoxi
Chiral ketone-catalyzed asymmetric epoxidation of olefins with Oxoneยฎ
โœ Koichiro Matsumoto; Kiyoshi Tomioka ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 64 KB

Chiral ketones 1 and 2 bearing 1-aza-7-oxabicyclo[3.5.0]decane skeleton and their C 2 -symmetric analogue 3 were readily prepared and evaluated as a chiral dioxirane precursor for asymmetric epoxidation of olefins with Oxone ยฎ . The ketone 2, bearing a diphenyl steric wall, was not effective and gav