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Asymmetric Epoxidation of Aldehydes Catalyzed by New C2-Symmetrical Chiral Sulfide.

✍ Scribed by Miyuki Ishizaki; Osamu Hoshino


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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Synthesis of novel C2-symmetrical chiral
✍ Miyuki Ishizaki; Osamu Hoshino πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 92 KB

## Abstract Novel C~2~‐symmetrical chiral sulfides were synthesized from (__R,R__)‐tartaric acid and their utility in the asymmetric epoxidation of aldehydes with benzyl bromide was examined. Among the sulfides used, silyl ether‐type sulfides were found to be superior to diol‐ and benzyl ether‐type