✦ LIBER ✦

Asymmetric electron spin relaxation in ClO2 solution. Deviation of the motional correlation time from modified Debye theory

✍ Scribed by L. Burlamacchi; M. Romanelli

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 242 KB
Volume: 10
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)80156-2

No coin nor oath required. For personal study only.

✦ Synopsis

In highly viscous soh~tions the FSR spectra of chlorine dioxide are asymmetrkally broadened. ModuIation of the anisotropic hyperfine aod g tensors accounts for the observed broadening but the correlation time for the motion is much smaller than expected from Debye theory. The calculated hydrodynamic radius is coplpared with that derived from spin rotational relaxation.