Asymmetric dissociation and bending potentials of H2S in the ground and excited electronic states

✍ Scribed by Giannoula Theodorakopoulos; Ioannis D. Petsalakis

• Publisher: Elsevier Science
• Year: 1991
• Tongue: English
• Weight: 617 KB
• Volume: 178
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(91)87005-v

✦ Synopsis

MRD CI calculations are presented on the asymmetric dissociation and the bending potentials of the ground and nine excited electronic states of H2S, at excitation energies under 9.0 eV. The results show that some similarities exist between the potentials of the states of H2S and those of HzO, but also some important differences. In particular, the bending potential of the 'B, state of H$ is rather flat, contrary to the assumptions of a bent geometry for this state in analyses of the photodissociation of HZS at 193 nm.