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Asymmetric dihydroxylations of allylic phosphine oxides

✍ Scribed by Adam Nelson; Peter O'Brien; Stuart Warren


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
229 KB
Volume
36
Category
Article
ISSN
0040-4039

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The asymmetric dihydroxylation of cis-al
✍ Michael S. VanNieuwenhze; K.Barry Sharpless πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 277 KB

The asymmetric dihydroxylation of several ck allylic alcohols is reported. The reactions proceed with moderate to good enantioselectivity. The enhanced enantioselection observed relatitie to other cis-olefin classes is believed to be dependent on the presence of the free hydroxyl group. A cis-hommll