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Asymmetric Diels-Alder reactions of 1,3-disiloxycyclohexadiene with chiral acrylamides

✍ Scribed by Hélène Lamy-Schelkens; Léon Ghosez

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
250 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

Diets-Alder reactions of 1,3-disiloxycyclohexadiene 2 with acrylamide a, derived from a chiral pyrrolidine possessing C2 symmetry, occur with high endo : exo and diastereofacial selectivities.

The endo : exo ratio is controlled by the choice of the catalyst.

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