Asymmetric Diels-Alder reaction: applications of chiral dienophiles
✍ Scribed by Masamune, Satoru; Reed, Lawrence A.; Davis, Jeffrey T.; Choy, William
- Book ID
- 118209529
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 505 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
AbstractÐA new synthetic method is developed for the asymmetric Diels±Alder reactions of acetylenic dienophiles. Acetylenic Fischer carbene complexes with chiral pyrrolidines as the heteroatom stabilizing substituent were anticipated to block three of the four possible approaches of a diene and lead
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract The Diels‐Alder reaction of __cis__‐5,6‐diacetoxy‐1,3‐cyclohexadiene (1), which has a __meso__ configuration, with the chiral nitroso dienophile 2 occurs with induction of four asymmetric centers in very high optical yield (ee = 94%) and leads to the dihydro oxazine 3 (89%). The influen