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Asymmetric Cyclopropanation with Diazoacetates Induced by Carbohydrate-Derived Chiral Auxiliaries.

โœ Scribed by Vitor F. Ferreira; Raquel A. C. Leao; Fernando de C. da Silva; Sergio Pinheiro; Paul Lhoste; Denis Sinou

Publisher
John Wiley and Sons
Year
2007
Weight
27 KB
Volume
38
Category
Article
ISSN
0931-7597

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Asymmetric Reactions Catalyzed by Chiral Metal Complexes. Part 77. Synthesis of an Axially Dissymmetric Biphenylcarboxylate Ligand, BDME, and Asymmetric Cyclopropanation of Olefins with Diazoacetate Catalyzed by Its Dirhodium(II) Complex. -The dirhodium complex of title ligand (R)-BDME serves as c