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Asymmetric Cyclopropanation of Styrenes Catalyzed by Metal Complexes of D2-Symmetrical Chiral Porphyrin: Superiority of Cobalt over Iron.

โœ Scribed by Ying Chen; X. Peter Zhang


Publisher
John Wiley and Sons
Year
2007
Weight
33 KB
Volume
38
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Reaction
โœ H. ISHITANI; K. ACHIWA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

Asymmetric Reactions Catalyzed by Chiral Metal Complexes. Part 77. Synthesis of an Axially Dissymmetric Biphenylcarboxylate Ligand, BDME, and Asymmetric Cyclopropanation of Olefins with Diazoacetate Catalyzed by Its Dirhodium(II) Complex. -The dirhodium complex of title ligand (R)-BDME serves as c